De-Slagging
De-slagging operations are carried
out to remove impurities from the furnace. During melting and refining
operations, some of the undesirable materials within the bath are oxidized and
enter the slag phase.
It is advantageous to remove as much
phosphorus into the slag as early in the heat as possible (i.e. while the bath
temperature is still low). The furnace is tilted backwards and slag is poured
out of the furnace through the slag door. Removal of the slag eliminates the
possibility of phosphorus reversion.
During slag foaming operations,
carbon may be injected into the slag where it will reduce FeO to metallic iron
and in the process produce carbon monoxide which helps foam the slag. If the
high phosphorus slag has not been removed prior to this operation, phosphorus
reversion will occur. During slag foaming, slag may overflow the sill level in
the EAF and flow out of the slag door.
The following table shows the
typical constituents of an EAF slag :
Component
|
Source
|
|
CaO
|
Charged
|
40 - 60 %
|
SiO2
|
Oxidation product
|
5 - 15 %
|
FeO
|
Oxidation product
|
10 - 30 %
|
MgO
|
Charged as dolomite
|
3 - 8 %
|
CaF2
|
Charged - slag fluidizer
|
|
MnO
|
Oxidation product
|
2 - 5%
|
S
|
Absorbed from steel
|
|
P
|
Oxidation product
|
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